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I reserve the right to headcanon that marijuana isn't that uncommon in Asgard and nobody can take that away from me. (I also feel like they'd be more partial to eating or drinking it rather than smoking it, but that's just me.)
I mean, with how liberal they seem to be with alcohol, I genuinely don't see how they wouldn't at least try other substances.
Not like that would necessarily even be a result of mortal influence from their visits to Midgard, either. They'd probably discover that kind of thing and enjoy it just on their own merit.
Personally speaking, I see Scarecrow as being a medicinal user of marijuana. He’s definitely not the ‘giggly pothead’ type. Not a Shaggy Rogers, if you will. But I can see him using it every so often for medicinal reasons.
This also aligns with headcanons involving him having autism and anxiety, both of which I subscribe to. Anxiety and Autism both being things marijuana is used for.
However, what people should be talking about is whether Marvel’s Thor or Loki would be. With how Asgard is in regards to alcohol, you can’t say they would be opposed to indulgence in other substances.
So, really, they must’ve at least tried it once-